(i) $H_3PO_{4\text{(aq)}} \rightleftharpoons H^+{_{\text{(aq)}}} + H_2PO_4^-{_{\text{(aq)}}}$
(ii) $H_2PO_4^-{_{\text{(aq)}}} \rightleftharpoons H^+{_{\text{(aq)}}} + HPO_4^{2-}{_{\text{(aq)}}}$
(iii) $HPO_4^{2-}{_{\text{(aq)}}} \rightleftharpoons H^+{_{\text{(aq)}}} + PO_4^{3-}{_{\text{(aq)}}}$
The equilibrium constants for the above reactions at a certain temperature are $K_1$,$K_2$,and $K_3$ respectively. The equilibrium constant for the reaction $H_3PO_{4\text{(aq)}} \rightleftharpoons 3H^{+}{_{\text{(aq)}}} + PO_4^{3-}{_{\text{(aq)}}}$
$K = K_1 \times K_2 \times K_3$ is

  • A
    $K_1 + K_2 + K_3$
  • B
    $\frac{K_1}{K_2 + K_3}$
  • C
    $\frac{K_3}{K_1 K_2}$
  • D
    $K_1 K_2 K_3$

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