When $SO_2$ gas is passed through an acidified solution of $K_2Cr_2O_7$,the solution turns........

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$Na_2CO_3 + Pb(NO_3)_2 \longrightarrow PbCO_3 \downarrow + 2NaNO_3$

Thiosulphate reacts differently with iodine and bromine in the reactions given below:
$2 S_2 O_3^{2-} + I_2 \rightarrow S_4 O_6^{2-} + 2 I^{-}$
$S_2 O_3^{2-} + 4 Br_2 + 5 H_2 O \rightarrow 2 SO_4^{2-} + 8 Br^{-} + 10 H^{+}$
Which of the following statements justifies the above dual behaviour of thiosulphate?

$50 \ mL$ of $0.1 \ M$ solution of a salt reacted with $25 \ mL$ of $0.1 \ M$ solution of sodium sulphite. The half-reaction for the oxidation of sulphite ion is:
$SO_{3}^{2-} (aq) + H_{2}O (l) \to SO_{4}^{2-} (aq) + 2H^{+} (aq) + 2e^{-}$
If the oxidation number of the metal in the salt was $+3$,what would be the new oxidation number of the metal?

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$Pb(CH_3COO)_2 + Na_2CrO_4 \longrightarrow PbCrO_4 \downarrow + 2CH_3COONa$

Why do the following reactions proceed differently? $Pb_{3}O_{4} + 8HCl \rightarrow 3PbCl_{2} + Cl_{2} + 4H_{2}O$ and $Pb_{3}O_{4} + 4HNO_{3} \rightarrow 2Pb(NO_{3})_{2} + PbO_{2} + 2H_{2}O$