$X$ (salt) + $AgNO_3$ $(aq.) \to \underset{(\text{Yellow ppt.})}{Y \downarrow}$ (soluble in excess of $NH_3$ solution). Salt $X$ does not contain:

  • A
    $PO_4^{3-}$
  • B
    $Br^{-}$
  • C
    $I^{-}$
  • D
    $AsO_3^{3-}$

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Which of the following is correctly matched?

In the qualitative analysis of nitrate,a brown ring is formed due to the formation of:

$A$ reagent consisting of $1$-naphthylamine and sulphanilic acid in acetic acid is used for the detection of:

Assertion $(A) :- Fe^{+3}$ is not used in the brown ring test for $NO_3^{-}$.
Reason $(R) :-$ Reduction of $NO_3^{-}$ takes place during the test.

The solution of a chemical compound $X$ reacts with $AgNO_3$ solution to form a white precipitate of $Y$,which dissolves in $NH_4OH$ to give a complex $Z$. When $Z$ is treated with dilute $HNO_3$,$Y$ reappears. The chemical compound $X$ can be:

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