$n-$Heptane $\xrightarrow[\Delta ]{Al_2O_3} P$ $\xrightarrow{[1 \ mole]}{NBS} Q$. Product $Q$ will be

Which best describes the product of the following reaction?
$Ph-C(CH_3)(Br)-CD_3 \xrightarrow{K^+ t-BuO^-, E_2} \text{product}$

Two bottles containing $C_6H_5I$ and $C_6H_5CH_2I$ have lost their original labels. They are labeled as $A$ and $B$ for testing. $A$ and $B$ are taken separately in test tubes and boiled with $NaOH$ solution. The final solution of each test tube is acidified with dilute $HNO_3$ and a little $AgNO_3$ is added. Solution $B$ gives a yellow precipitate. Which of the following statements is correct?

The reaction of $t-$butyl bromide with sodium methoxide mainly gives .............

$CH_3-CH_2-Br + Nu^{\Theta} \rightarrow CH_3-CH_2-Nu + Br^{\Theta}$
The decreasing order of the reaction rate with nucleophile $Nu^{\Theta}$ is $Nu^{\Theta} = (I) PhO^{\Theta}; (II) CH_3COO^{\Theta}; (III) OH^{\Theta}; (IV) CH_3O^{\Theta}$

Identify the product $A$ in the following reaction: $C_2H_5Br + \text{aq. } KOH \rightarrow A + KBr$