$N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}; K_1$
$NH_{3(g)} \rightleftharpoons \frac{1}{2} N_{2(g)} + \frac{3}{2} H_{2(g)}; K_2$
$\frac{1}{2} N_{2(g)} + \frac{3}{2} H_{2(g)} \rightleftharpoons NH_{3(g)}; K_3$
$2NH_{3(g)} \rightleftharpoons N_{2(g)} + 3H_{2(g)}; K_4$
If $K_1 = K_2^x = K_3^y = K_4^z$,then the correct values of $x, y,$ and $z$ are respectively:

  • A
    $-2, 2, -1$
  • B
    $-1, 2, -2$
  • C
    $-2, 2, 1$
  • D
    $2, 1, -2$

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Assertion: Reaction quotient is defined in the same way as equilibrium constant at any stage of the reaction.
Reason: If $Q_c < K_c$,the reaction moves in the direction of reactants.

The dissociation of $SO_{3(g)}$ into $SO_{2(g)}$ and $O_{2(g)}$ is carried out in a closed container at a constant temperature $T$. The equilibrium constant for the reaction is $K_P = x \ atm$. The partial pressure variation for the three gases is as shown in the graph. The value of $x$ is

The following equilibria are given:
$N_2 + 3H_2 \rightleftharpoons 2NH_3 ; K_1$
$N_2 + O_2 \rightleftharpoons 2NO ; K_2$
$H_2 + \frac{1}{2}O_2 \rightleftharpoons H_2O ; K_3$
The equilibrium constant of the reaction $2NH_3 + \frac{5}{2}O_2 \rightleftharpoons 2NO + 3H_2O$ in terms of $K_1, K_2$ and $K_3$ is:

At a definite temperature,the $K_c$ of the following reaction is $0.18$: $PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$. In a reaction mixture at the same temperature,$[PCl_3] = 0.042 \ M$,$[Cl_2] = 0.024 \ M$,and $[PCl_5] = 0.005 \ M$. Is this reaction in equilibrium? In which direction will the reaction proceed?

Consider the following gaseous equilibrium reactions $(I)$,$(II)$ and $(III)$ with equilibrium constants $K_1$,$K_2$ and $K_3$ respectively:
$I$) $\frac{1}{2} N_2 + \frac{3}{2} H_2 \rightleftharpoons NH_3$
$II$) $2 NO \rightleftharpoons N_2 + O_2$
$III$) $H_2 + \frac{1}{2} O_2 \rightleftharpoons H_2 O$
The correct expression for the equilibrium constant for the gaseous equilibrium reaction $2 NH_3 + \frac{5}{2} O_2 \rightleftharpoons 2 NO + 3 H_2 O$ is

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