Which of the following will not give a white | vedclass

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(D) The reaction of coordination compounds with silver nitrate $(AgNO_3)$ depends on the presence of ionizable chloride ions $(Cl^-)$ outside the coor

Vedclass · Accepted Answer

$[Co(NH_3)_3Cl_3]$

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(D) The reaction of coordination compounds with silver nitrate $(AgNO_3)$ depends on the presence of ionizable chloride ions $(Cl^-)$ outside the coordination sphere.If $Cl^-$ ions are present outside the coordination sphere,they react with $Ag^+$ to form a white precipitate of silver chloride $(AgCl)$.$1$. $[Co(NH_3)_6]Cl_3$ gives $3$ moles of $Cl^-$ ions.$2$. $[Co(NH_3)_5Cl]Cl_2$ gives $2$ moles of $Cl^-$ ions.$3$. $[Co(NH_3)_4Cl_2]Cl$ gives $1$ mole of $Cl^-$ ions.$4$. $[Co(NH_3)_3Cl_3]$ has no $Cl^-$ ions outside the coordination sphere,so it will not give a white precipitate with $AgNO_3$.

Which of the following will not give a white precipitate with silver nitrate $(AgNO_3)$?

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