$CN^{-}$ ligand containing complexes are generally ...... .

  • A
    High spin complex
  • B
    Low spin complex
  • C
    Both $(A)$ and $(B)$
  • D
    None of these

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Using crystal field theory,draw energy level diagrams,write the electronic configuration of the central metal atom/ion,and determine the magnetic moment value for the following:
$(i)$ $[CoF_{6}]^{3-}, [Co(H_{2}O)_{6}]^{2+}, [Co(CN)_{6}]^{3-}$
$(ii)$ $[FeF_{6}]^{3-}, [Fe(H_{2}O)_{6}]^{2+}, [Fe(CN)_{6}]^{4-}$

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Calculate the Crystal Field Stabilization Energy $(CFSE)$ for a high-spin $d^4$ tetrahedral complex.

Match the following complexes in List-$I$ with their electronic configurations in List-$II$.
List-$I$ (Complex)List-$II$ (Electronic configuration of metal/ion)
$A. [Co(NH_3)_6]^{3+}$$I. t_{2g}^5 e_g^0$
$B. [CoF_6]^{3-}$$II. t_{2g}^6 e_g^0$
$C. [Ni(CO)_4]$$III. t_{2g}^4 e_g^2$
$D. [Fe(CN)_6]^{3-}$$IV. t^4 e^6$

State the limitations of crystal field theory $(CFT)$.

Complexes containing halide ligands are generally .....

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