$A$ mixture $X$ containing $0.02 \, mol$ of $[Co(NH_3)_5SO_4]Br$ and $0.02 \, mol$ of $[Co(NH_3)_5Br]SO_4$ is dissolved in water to make a $2 \, L$ solution.
$1 \, L \, of \, X + \text{Excess of } AgNO_3 \rightarrow Y \, mol \, of \, ppt.$
$1 \, L \, of \, X + \text{Excess of } BaCl_2 \rightarrow Z \, mol \, of \, ppt.$
Then $Y$ and $Z$ are respectively ...............

When potassium iodide is added to an aqueous solution of potassium ferricyanide,a reversible reaction is observed in which a complex $P$ is formed. In a strong acidic medium,the equilibrium shifts completely towards $P$. Addition of zinc chloride to $P$ in a slightly acidic medium results in a sparingly soluble complex $Q$.
$(1)$ The number of moles of potassium iodide required to produce two moles of $P$ is. . .
$(2)$ The number of zinc ions present in the molecular formula of $Q$ is. . . .
Give the answer for $(1)$ and $(2)$.

Which of the following statements is correct?

Match the following complexes in List-$I$ with their colors in List-$II$:

List-$I$ (Complex)	List-$II$ (Color)
$A. [Ni(en)_3]^{2+}$	$I. \text{Green}$
$B. [Ni(H_2O)_4(en)]^{2+}$	$II. \text{Blue}$
$C. [Ni(H_2O)_6]^{2+}$	$III. \text{Pale blue}$
$D. [Ni(H_2O)_2(en)_2]^{2+}$	$IV. \text{Violet}$

Which of the following compounds is brown coloured?

Given below are two statements:
Statement $I$: Crystal Field Stabilization Energy $(CFSE)$ of $[Cr(H_2O)_6]^{2+}$ is greater than that of $[Mn(H_2O)_6]^{2+}$.
Statement $II$: Potassium ferricyanide has a greater spin-only magnetic moment than sodium ferrocyanide.
In the light of the above statements, choose the correct answer from the options given below: