Which of the following is the strongest ortho-para directing group?

The major product of the following reaction is:

Which product is obtained when chlorobenzene is reacted with $6-8\%$ aqueous $NaOH$ at $633\,K$ temperature and $300\,bar$ pressure in the presence of an acid catalyst?

Compound $A$ $(C_7H_8O)$ is insoluble in water,dilute $HCl$,and aqueous $NaHCO_3$,but it dissolves in dilute $NaOH$. When $A$ is treated with $Br_2$ water,it is converted into a compound $C_7H_5OBr_3$ rapidly. The structure of $A$ is

Which of the following is the correct decreasing order of acidic strength for the compounds listed below?
$I$: $p$-chlorophenol
$II$: $p$-Cresol
$III$: $p$-nitrophenol
$IV$: $p$-methoxyphenol

$Phenol$ $\xrightarrow[Distillation]{Zn} A$ $\xrightarrow[Conc. H_2SO_4]{Conc. HNO_3} B$ $\xrightarrow[NaOH]{Zn} C$
In the above reaction,$A$,$B$,and $C$ are the following compounds: