Which of the following groups deactivates the benzene ring towards electrophilic substitution reaction?

  • A
    Methyl
  • B
    Amino
  • C
    Hydroxyl
  • D
    Chloro

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Assertion : $4-$Nitrochlorobenzene undergoes nucleophilic substitution more readily than chlorobenzene.
Reason : Chlorobenzene undergoes nucleophilic substitution by elimination-addition mechanism while $4-$nitrochlorobenzene undergoes nucleophilic substitution by addition-elimination mechanism.

Explain why aryl halides are extremely less reactive towards nucleophilic substitution reactions.

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