Which of the following ions is paramagnetic?

In which of the $f$-block elements is the number of electrons in the $(n-2)f$ subshell zero?

Which of the following substances is not paramagnetic?

For $M^{2+} / M$ and $M^{3+} / M^{2+}$ systems,the ${E^{\Theta}}$ values for some metals are as follows:
$Cr^{2+} / Cr : -0.9 \ V$
$Cr^{3+} / Cr^{2+} : -0.4 \ V$
$Mn^{2+} / Mn : -1.2 \ V$
$Mn^{3+} / Mn^{2+} : +1.5 \ V$
$Fe^{2+} / Fe : -0.4 \ V$
$Fe^{3+} / Fe^{2+} : +0.8 \ V$
Use this data to comment upon:
$(i)$ The stability of $Fe^{3+}$ in acid solution as compared to that of $Cr^{3+}$ or $Mn^{3+}$ and
$(ii)$ The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.

The highest magnetic moment is shown by the transition metal ion with the outer electronic configuration

Why is the first ionisation enthalpy of $Cr$ lower than that of $Zn$?