When an aqueous solution of glucose is frozen,which crystals will separate out first?

The freezing point of a solution containing $10 \ mL$ of non-volatile and non-electrolyte liquid $A$ in $500 \ g$ of water is $-0.413^{\circ} C$. If $K_f$ of water is $1.86 \ K \ kg \ mol^{-1}$ and the molecular weight of $A = 60 \ g \ mol^{-1}$, what is the density of the solution in $g \ mL^{-1}$? (Assume $\Delta_{\text{mix}} V = 0$)

The depression in freezing point of water observed for the same amount of acetic acid,trichloroacetic acid,and trifluoroacetic acid increases in the order given above. Explain briefly.

$6 \ g$ of a non-volatile,non-electrolyte $X$ dissolved in $100 \ g$ of water freezes at $-0.93^{\circ} C$. The molar mass of $X$ in $g \ mol^{-1}$ is ($K_f$ of $H_2O = 1.86 \ K \ kg \ mol^{-1}$)

The aqueous solution of urea has a freezing point of $-0.6\,^\circ C$. To prepare such a solution,how many grams of urea are needed to dissolve in $3\,kg$ of water? $(M = 60\,g\,mol^{-1}, K_{f} = 1.5\,^\circ C\,kg\,mol^{-1})$

Calculate the molality of the solution of a nonvolatile solute if it freezes at $-0.36 \ ^{\circ}C$. [Given: $K_{f}$ for solvent $= 1.86 \ K \ kg \ mol^{-1}$]