Calculate the freezing point in $^oC$ of an aqueous solution of urea that boils at $100.18\,^oC$. $(K_f = 1.86\, ^oC\, m^{-1}, K_b = 0.512\,^oC\, m^{-1})$

The solution from the following with the highest depression in freezing point (lowest freezing point) is:

In the depression of freezing point experiment,it is found that the:

Assertion : If one component of a solution obeys Raoult's law over a certain range of composition,the other component will not obey Henry's law in that range.
Reason : Raoult's law is a special case of Henry's law.

The $pH$ of a $0.1 \, M$ monobasic acid is measured to be $2$. Its osmotic pressure at a given temperature $T \, K$ is (in $, RT$)

$1 \ g$ of silver gets distributed between $10 \ cm^3$ of molten zinc and $100 \ cm^3$ of molten lead at $800^{\circ} C$. The percentage of silver in the zinc layer is approximately