$[Cr(NH_3)_6]^{3+}$ is paramagnetic while $[Ni(CN)_4]^{2-}$ is diamagnetic. Explain why?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) In $[Cr(NH_3)_6]^{3+}$,$Cr$ is in the $+3$ oxidation state,which corresponds to a $d^3$ configuration.
$NH_3$ is a ligand that forms an octahedral complex. The $Cr^{3+}$ ion undergoes $d^2sp^3$ hybridization.
Since there are $3$ unpaired electrons in the $3d$ orbitals,the complex is paramagnetic.
In $[Ni(CN)_4]^{2-}$,$Ni$ is in the $+2$ oxidation state,which corresponds to a $d^8$ configuration.
$CN^-$ is a strong field ligand that causes the pairing of electrons in the $3d$ orbitals.
After pairing,the $Ni^{2+}$ ion undergoes $dsp^2$ hybridization to form a square planar complex.
As there are no unpaired electrons,the complex is diamagnetic.

Explore More

Similar Questions

Coordination isomerism is formed by the interchange of ligands between which of the following?

Which of the following complexes shows optical isomerism?

Calculate the total number of stereoisomers for the octahedral complex $[Fe(F)(Cl)(Br)(I)(NH_3)(H_2O)]^-$.

The type of isomerism between $[Co(en)_2(NCS)_2]Cl$ and $[Co(en)_2(NCS)Cl]NCS$ is ............ .

Identify the ion (hydrated in solution) which is not correctly matched with its spin only magnetic moment (in $BM$) given in brackets.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo