Write the equation relating thermodynamics and electrochemistry.

Review the $SRP$ (at $25\,\text{°C}$) data in acidic medium:
$Ti^{4+} + e^- \to Ti^{3+}, \, E^o = -x \text{ V}$
$Fe^{3+} + e^- \to Fe^{2+}, \, E^o = -y \text{ V}$
where $x < y$,point out the wrong statement.

How would you determine the standard electrode potential of the system $Mg^{2+} | Mg$?

$Cu^{+} + e^- \to Cu$ ; $E^o = X_1 \ V$
$Cu^{2+} + 2e^- \to Cu$ ; $E^o = X_2 \ V$
Then for $Cu^{2+} + e^- \to Cu^{+}$ ; $E^o$ will be ?

Give the symbolic representation of the following half-cells (electrodes):
$(i)$ $2H^{+}_{(aq)} + 2e^- \to H_{2_{(g)}}$
$(ii)$ $Br_{2_{(aq)}} + 2e^- \to 2Br^{-}_{(aq)}$
$(iii)$ $2Br^{-}_{(aq)} \to Br_{2_{(aq)}} + 2e^-$

Which metal cannot produce $H_2$ gas by reaction with $HCl$ solution?
$E^0_{Fe^{2+}/Fe} = -0.44 \ V$
$E^0_{Cu^{2+}/Cu} = +0.34 \ V$
$E^0_{Ni^{2+}/Ni} = -0.25 \ V$
$E^0_{Zn^{2+}/Zn} = -0.76 \ V$