Briefly explain the Valence Bond Theory $(VBT)$.

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(N/A) According to this theory,the metal atom or ion under the influence of ligands uses its $(n-1)d, ns, np$ or $ns, np, nd$ orbitals for hybridization to produce a set of equivalent orbitals of definite geometry such as octahedral,square planar,and others (as shown in the table below).
Coordination NumberType of HybridizationDistribution of Hybrid Orbitals in Space
$4$$sp^3$Tetrahedral
$4$$dsp^2$Square planar
$5$$sp^3d$Trigonal bipyramidal
$6$$sp^3d^2$Octahedral
$6$$d^2sp^3$Octahedral

These hybrid orbitals are allowed to overlap with ligand orbitals that can donate electron pairs for bonding.

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Match the coordination number and type of hybridisation with the distribution of hybrid orbitals in space based on Valence Bond Theory.
Coordination number and type of hybridisation Distribution of hybrid orbitals in space
$a. 4, sp^3$ $i. \text{trigonal bipyramidal}$
$b. 4, dsp^2$ $ii. \text{octahedral}$
$c. 5, sp^3d$ $iii. \text{tetrahedral}$
$d. 6, d^2sp^3$ $iv. \text{square planar}$

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