Given the equilibrium constants for the following three reactions:
$(1) N_2 + 3H_2 \rightleftharpoons 2NH_3; K_1$
$(2) N_2 + O_2 \rightleftharpoons 2NO; K_2$
$(3) H_2 + \frac{1}{2}O_2 \rightleftharpoons H_2O; K_3$
The equilibrium constant for the reaction of $NH_3$ with oxygen to form $NO$ and $H_2O$ is:

$CH_3COOH_{(l)} + C_2H_5OH_{(l)} \rightleftharpoons CH_3COOC_2H_{5_{(l)}} + H_2O_{(l)}$. In the above reaction,one mole of each of acetic acid and alcohol are heated in the presence of a little conc. $H_2SO_4$. On equilibrium being attained:

For the reaction $C_{(s)} + CO_{2(g)} \rightleftharpoons 2CO_{(g)}$,if $25\%$ of $CO_2$ is converted to $CO$ at equilibrium and the total equilibrium pressure is $12 \ atm$,then the partial pressure of $CO_2$ at equilibrium will be............$atm$.

In a chemical reaction $A + 2B \rightleftharpoons 2C + D$,the initial concentration of $B$ was $1.5$ times of $A$ but the equilibrium concentrations of $A$ and $B$ were found to be equal. The equilibrium constant $(K)$ for the aforesaid chemical reaction is

$S_1$: In case of endothermic reactions,the equilibrium shifts in the forward direction on increasing temperature.
$S_2$: The value of $K_{eq}$ depends only on temperature and is independent of pressure.
$S_3$: For the reaction,$H_2(g) + I_2(g) \rightleftharpoons 2HI(g)$,the equilibrium constant,$K_{eq}$ is dimensionless because the number of moles of gaseous products equals the number of moles of gaseous reactants.

The two substances $A$ and $B$ are in equilibrium with $C$ and $D$ as $2A + B \rightleftharpoons 3C + 2D$. If the initial pressure of $A$ and $B$ are in the ratio of $4:1$ and at equilibrium,the partial pressures of $A$ and $D$ are equal,find the correct relation.