In the titration of $KMnO_{4}$ with $C_{2}O_{4}^{2-}$,which temperature range is not proper? Why?

In a titration experiment,$10 \, mL$ of an $FeCl_{2}$ solution consumed $25 \, mL$ of a standard $K_{2}Cr_{2}O_{7}$ solution to reach the equivalence point. The standard $K_{2}Cr_{2}O_{7}$ solution is prepared by dissolving $1.225 \, g$ of $K_{2}Cr_{2}O_{7}$ in $250 \, mL$ water. The concentration of the $FeCl_{2}$ solution is closest to $..... \, N$
[Given : molecular weight of $K_{2}Cr_{2}O_{7} = 294 \, g \, mol^{-1}$]

$10.0 \, mL$ of $0.05 \, M \, KMnO_4$ solution was consumed in a titration with $10.0 \, mL$ of given oxalic acid dihydrate solution. The strength of given oxalic acid solution is $..... \times 10^{-2} \, g / L$ (Round off to the nearest integer).

In a conductometric titration,a small volume of titrant of higher concentration is added stepwise to a larger volume of titrate of much lower concentration,and the conductance is measured after each addition.
The limiting ionic conductivity ( $\Lambda ^0$ ) values (in $mS \ m ^2 \ mol ^{-1}$ ) for different ions in aqueous solutions are given below:

Ions	$Ag ^{+}$	$K ^{+}$	$Na ^{+}$	$H ^{+}$	$NO _3^{-}$	$Cl ^{-}$	$SO _4^{2-}$	$OH ^{-}$	$CH _3COO ^{-}$
$\Lambda _0$	$6.2$	$7.4$	$5.0$	$35.0$	$7.2$	$7.6$	$16.0$	$19.9$	$4.1$

For different combinations of titrates and titrants given in List-$I$,the graphs of 'conductance' versus 'volume of titrant' are given in List-$II$.

List-$I$	List-$II$
$(P)$ Titrate: $KCl$,Titrant: $AgNO _3$	$(1)$ Graph showing initial decrease then increase
$(Q)$ Titrate: $AgNO _3$,Titrant: $KCl$	$(2)$ Graph showing sharp decrease then sharp increase
$(R)$ Titrate: $NaOH$,Titrant: $HCl$	$(3)$ Graph showing slight decrease then increase
$(S)$ Titrate: $NaOH$,Titrant: $CH _3COOH$	$(4)$ Graph showing continuous increase
	$(5)$ Graph showing decrease then constant

Match each entry in List-$I$ with the appropriate entry in List-$II$ and choose the correct option.

In the titration of potassium permanganate $(KMnO_4)$ against ferrous ammonium sulphate $(FAS)$ solution,dilute sulphuric acid $(H_2SO_4)$ but not nitric acid $(HNO_3)$ is used to maintain an acidic medium,because:

$0.4 \ g$ mixture of $NaOH, Na_{2}CO_{3}$ and some inert impurities was first titrated with $\frac{N}{10} \ HCl$ using phenolphthalein as an indicator,$17.5 \ mL$ of $HCl$ was required at the end point. After this,methyl orange was added and titrated. $1.5 \ mL$ of same $HCl$ was required for the next end point. The weight percentage of $Na_{2}CO_{3}$ in the mixture is .......... (Rounded-off to the nearest integer)