$[X] + H_2SO_4 \to [Y]$ (a colourless gas with irritating smell).
$[Y] + K_2Cr_2O_7 + H_2SO_4 \to$ green solution.
$[X]$ and $[Y]$ are:

  • A
    $SO_3^{2-}, SO_2$
  • B
    $Cl^{-}, HCl$
  • C
    $S^{2-}, H_2S$
  • D
    $CO_3^{2-}, CO_2$

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$A$ chloride salt solution acidified with dil. $HNO_3$ gives a curdy white precipitate,$[A]$,on addition of $AgNO_3$. $[A]$ on treatment with $NH_4OH$ gives a clear solution,$B$. Identify $[A]$ and $B$.

$H_2S$ gas is not evolved when $SO_3^{2-}$ ion reacts with the following reagents.

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