$\Delta H$ and $\Delta E$ for the reaction,$Fe_{2}O_{3(s)} + 3H_{2(g)} \rightarrow 2Fe_{(s)} + 3H_{2}O_{(l)}$ at constant temperature are related as

The heat liberated when $1.89 \ g$ of benzoic acid is burnt in a bomb calorimeter at $25^{\circ} C$ increases the temperature of $18.94 \ kg$ of water by $0.632^{\circ} C$. If the specific heat of water at $25^{\circ} C$ is $0.998 \ cal / (g^{\circ} C)$,then find the heat of combustion of benzoic acid.

An ideal gas undergoes a cyclic process as shown in the figure.
$\Delta U_{BC} = -5 \ kJ \ mol^{-1}$,$q_{AB} = 2 \ kJ \ mol^{-1}$
$\Delta W_{AB} = -5 \ kJ \ mol^{-1}$,$W_{CA} = 3 \ kJ \ mol^{-1}$
Heat absorbed by the system during process $CA$ is......$kJ \ mol^{-1}$

The difference between the reaction enthalpy change $(\Delta _r H)$ and reaction internal energy change $(\Delta _r U)$ for the reaction $2C_6H_{6(l)} + 15O_{2(g)} \longrightarrow 12CO_{2(g)} + 6H_2O_{(l)}$ at $300 \ K$ is $....$ $J \ mol^{-1}$ $(R = 8.314 \ J \ mol^{-1} \ K^{-1})$

For the reactions,$C + O_2 \to CO_2; \Delta H = -393 \ J$
$2Zn + O_2 \to 2ZnO; \Delta H = -412 \ J$

Match the transformations in column $I$ with appropriate options in column $II$.

Column $I$	Column $II$
$A$. $CO_{2(s)} \rightarrow CO_{2(g)}$	$p$. phase transition
$B$. $CaCO_{3(s)} \rightarrow CaO_{(s)} + CO_{2(g)}$	$q$. allotropic change
$C$. $2H_{(g)} \rightarrow H_{2(g)}$	$r$. $\Delta H$ is positive
$D$. $P_{(\text{white, solid})} \rightarrow P_{(\text{red, solid})}$	$s$. $\Delta S$ is positive
	$t$. $\Delta S$ is negative