$A$ vessel at $1000 \ K$ contains $CO_2$ with a pressure of $0.5 \ atm$. Some of $CO_2$ is converted into $CO$ on addition of graphite. If total pressure at equilibrium is $0.8 \ atm$,then $K_P$ is : (in $atm$)

  • A
    $0.18$
  • B
    $1.8$
  • C
    $0.3$
  • D
    $3$

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At $473 \ K$,the equilibrium constant $K_{c}$ for the decomposition of phosphorus pentachloride is $8.3 \times 10^{-3}$. If the decomposition is depicted as:
$PCl_{5(g)} \longleftrightarrow PCl_{3(g)} + Cl_{2(g)} \quad \Delta_{r}H^{\circ} = 124.0 \ kJ \ mol^{-1}$
$(a)$ Write an expression for $K_{c}$ for the reaction.
$(b)$ What is the value of $K_{c}$ for the reverse reaction at the same temperature?
$(c)$ What would be the effect on $K_{c}$ if:
$(i)$ more $PCl_{5}$ is added?
$(ii)$ pressure is increased?
$(iii)$ the temperature is increased?

$0.6 \ mol$ of $NH_3$ in a reaction vessel of $2 \ dm^3$ capacity was brought to equilibrium. The vessel was then found to contain $0.15 \ mol$ of $H_2$ formed by the reaction $2NH_{3(g)} \rightleftharpoons N_{2(g)} + 3H_{2(g)}$. Which of the following statements is true?

$8 \ mol$ of $AB_{3(g)}$ are introduced into a $1.0 \ dm^3$ vessel. If it dissociates as $2AB_{3(g)} \rightleftharpoons A_{2(g)} + 3B_{2(g)}$. At equilibrium,$2 \ mol$ of $A_2$ are found to be present. The equilibrium constant of this reaction is

The equilibrium constants for the following three reactions $(i)$,$(ii)$,and $(iii)$ are given as:
$(i)$ $CO_{(g)} + H_2O_{(g)} \rightleftharpoons CO_{2(g)} + H_{2(g)} \quad K_1$
$(ii)$ $CH_{4(g)} + H_2O_{(g)} \rightleftharpoons CO_{(g)} + 3H_{2(g)} \quad K_2$
$(iii)$ $CH_{4(g)} + 2H_2O_{(g)} \rightleftharpoons CO_{2(g)} + 4H_{2(g)} \quad K_3$
Which of the following relations is correct?

Calculate the partial pressure of carbon monoxide from the following data:
$CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}, K_p = 8 \times 10^{-2}$
$CO_{2(g)} + C_{(s)} \rightleftharpoons 2CO_{(g)}, K_p = 2$

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