$1.2 \ g$ of an organic compound on Kjeldahlization liberates ammonia which consumes $30 \ cm^3$ of $1 \ N \ HCl$. The percentage of nitrogen in the organic compound is:

In the Kjeldahl's method for estimation of nitrogen present in a soil sample,ammonia evolved from $0.75 \ g$ of sample neutralized $10 \ mL$ of $1 \ M \ H_2SO_4$. The percentage of nitrogen in the soil is (in $.33$)

$0.25 \ g$ of an organic compound containing chlorine gave $0.40 \ g$ of silver chloride in Carius estimation. The percentage of chlorine present in the compound is $.....$ [in nearest integer].
(Given: Molar mass of $Ag$ is $108 \ g \ mol^{-1}$ and that of $Cl$ is $35.5 \ g \ mol^{-1}$)

The Kjeldahl method of nitrogen estimation fails for which of the following reaction products $?$
$(a)$ Nitrobenzene $\xrightarrow{Sn/HCl}$ Aniline
$(b)$ Benzonitrile $\xrightarrow{LiAlH_4}$ Benzylamine
$(c)$ Benzyl cyanide $\xrightarrow{(i) SnCl_2 + HCl, (ii) H_2O}$ Phenylacetaldehyde
$(d)$ Aniline $\xrightarrow{NaNO_2/HCl}$ Benzenediazonium chloride

$A$ sample of $0.50 \, g$ of an organic compound was treated according to Kjeldahl's method. The ammonia evolved was absorbed in $50 \, mL$ of $0.5 \, M \, H_{2}SO_{4}$. The residual acid required $60 \, mL$ of $0.5 \, M \, NaOH$ solution for neutralisation. Find the percentage composition of nitrogen in the compound. (in $\%$)

In the sulphur estimation,$0.471 \, g$ of an organic compound gave $1.44 \, g$ of barium sulphate. The percentage of sulphur in the compound is $...... \%$. (Nearest integer)
(Atomic Mass of $Ba=137 \, u$)