When $2 \ mol$ of $C_2H_{6(g)}$ is completely combusted,it releases $3129 \ kJ$ of heat. What is the enthalpy of formation of $C_2H_{6(g)}$? The $\Delta H_f$ values for $CO_{2(g)}$ and $H_2O_{(l)}$ are $-395 \ kJ \ mol^{-1}$ and $-286 \ kJ \ mol^{-1}$ respectively.

  • A
    $-71.3$
  • B
    $-82.3$
  • C
    $-81.7$
  • D
    $-83.5$

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The enthalpies of formation of $CO_{2(g)}$ and $CaO_{(s)}$ are $-94.0 \, kJ$ and $-152 \, kJ$ respectively. The enthalpy of the reaction $CaCO_{3(s)} \rightarrow CaO_{(s)} + CO_{2(g)}$ is $42 \, kJ$. The enthalpy of formation of $CaCO_{3(s)}$ is ............... $kJ$.

Calculate the standard enthalpy of formation of $CH_{3}OH_{(l)}$ from the following data:
$CH_{3}OH_{(l)} + \frac{3}{2} O_{2_{(g)}} \rightarrow CO_{2_{(g)}} + 2 H_{2}O_{(l)}$; $\Delta_{r} H^{\ominus} = -726 \ kJ \ mol^{-1}$
$C_{(graphite)} + O_{2_{(g)}} \rightarrow CO_{2_{(g)}}$; $\Delta_{c} H^{\ominus} = -393 \ kJ \ mol^{-1}$
$H_{2_{(g)}} + \frac{1}{2} O_{2_{(g)}} \rightarrow H_{2}O_{(l)}$; $\Delta_{f} H^{\ominus} = -286 \ kJ \ mol^{-1}$

At $298 \ K$ and constant pressure, the heat of formation of $C_2H_{2(g)}$ and $C_6H_{6(g)}$ is $230 \ kJ \ mol^{-1}$ and $85 \ kJ \ mol^{-1}$ respectively. What will be the change in heat for the reaction?
$3 \ C_2H_{2(g)} \rightarrow C_6H_{6(g)}$

At $300 \, K$,the standard enthalpies of formation of $C_6H_5COOH_{(s)}$,$CO_{2_{(g)}}$,and $H_2O_{(l)}$ are $-408$,$-393$,and $-286 \, kJ \, mol^{-1}$ respectively. What is the heat of combustion of benzoic acid at constant volume in $kJ$ (in $.75$)? $(R = 8.31 \, J \, mol^{-1} \, K^{-1})$

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Calculate the heat of reaction for the process: $NH_3(g) + HCl(g) \rightarrow NH_4Cl(s)$ given the following data:
$(i)$ $NH_3(g) + aq \rightarrow NH_3(aq)$,$\Delta H = -8.4 \, Kcal$
$(ii)$ $HCl(g) + aq \rightarrow HCl(aq)$,$\Delta H = -17.3 \, Kcal$
$(iii)$ $NH_3(aq) + HCl(aq) \rightarrow NH_4Cl(aq)$,$\Delta H = -12.5 \, Kcal$
$(iv)$ $NH_4Cl(s) + aq \rightarrow NH_4Cl(aq)$,$\Delta H = +3.9 \, Kcal$ (in $, Kcal$)

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