If the ratio of bond dissociation energies of $XY$,$X_2$,and $Y_2$ is $1 : 1 : 0.5$ and the enthalpy of formation of $XY$ is $\Delta_f H = -200 \ kJ \ mol^{-1}$,then the bond dissociation energy of $X_2$ in $kJ \ mol^{-1}$ is:

  • A
    $100$
  • B
    $800$
  • C
    $300$
  • D
    $400$

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The bond enthalpies of $C-C, C=C, H-H$ and $C-H$ bonds are $360, 600, 400$ and $410 \ kJ \ mol^{-1}$ respectively. What is the heat of hydrogenation of ethylene?

Identify the molecule for which the enthalpy of atomization $\left(\Delta_{a} H^{\ominus}\right)$ and bond dissociation enthalpy $\left(\Delta_{BOND} H^{\ominus}\right)$ are not equal.

When $1 \, \text{mol}$ of anhydrous salt $AB$ is dissolved in water,$21.0 \, J \, \text{mol}^{-1}$ of heat is released. The enthalpy of hydration of $AB$ is $-29.4 \, J \, \text{mol}^{-1}$. What is the enthalpy of solution of the hydrated salt $AB \cdot 2H_2O_{(s)}$ in $J \, \text{mol}^{-1}$ (in $.4$)?

Calculate the heat of formation for propene $(C_3H_6)$ using the following thermochemical equations:
$(i) C_{(s)} + O_{2(g)} \to CO_{2(g)}; \Delta H_1 = -94.05 \ k.cal/mole$
$(ii) H_{2(g)} + \frac{1}{2} O_{2(g)} \to H_2O_{(l)}; \Delta H_2 = -68.32 \ k.cal/mole$
$(iii) C_3H_{6(g)} + \frac{9}{2} O_{2(g)} \to 3 CO_{2(g)} + 3 H_2O_{(l)}; \Delta H_3 = -499.7 \ k.cal/mole$
(Note: The original question provided propane combustion data; assuming propene combustion data for consistency).

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Three thermochemical equations are given below:
$(i) C_{(graphite)} + O_{2(g)} \to CO_{2(g)}; \Delta_r H^\circ = x \ kJ \ mol^{-1}$
$(ii) C_{(graphite)} + \frac{1}{2} O_{2(g)} \to CO_{(g)}; \Delta_r H^\circ = y \ kJ \ mol^{-1}$
$(iii) CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)}; \Delta_r H^\circ = z \ kJ \ mol^{-1}$
Based on the above equations,find out which of the relationship given below is correct.

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