How much heat in $KJ$ is released during the combustion of $112 \ L$ of water gas at $S.T.P.$? (Water gas is an equimolar mixture of $H_2$ and $CO$)
$H_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow H_2O_{(g)}; \Delta H = -241.8 \ KJ$
$CO_{(g)} + \frac{1}{2} O_{2(g)} \rightarrow CO_{2(g)}; \Delta H = -283 \ KJ$

Match the transformations in column $I$ with appropriate options in column $II$.

Column $I$	Column $II$
$A$. $CO_{2(s)} \rightarrow CO_{2(g)}$	$p$. phase transition
$B$. $CaCO_{3(s)} \rightarrow CaO_{(s)} + CO_{2(g)}$	$q$. allotropic change
$C$. $2H_{(g)} \rightarrow H_{2(g)}$	$r$. $\Delta H$ is positive
$D$. $P_{(\text{white, solid})} \rightarrow P_{(\text{red, solid})}$	$s$. $\Delta S$ is positive
	$t$. $\Delta S$ is negative

When $2.0 \ g$ of sucrose is oxidized to form $CO_{2(g)}$ and $H_2O(\ell)$,the internal energy changes by $-24 \ kJ$. Calculate the value of $\Delta H$ at $298 \ K$ in $kJ \ mol^{-1}$. (Molar mass of sucrose $= 342 \ g \ mol^{-1}$)

For the reaction $2C_6H_6(l) + 15O_2(g) \rightarrow 12CO_2(g) + 6H_2O(l)$ at $25 \ ^\circ C$,calculate the difference between the heat of reaction at constant volume and constant pressure in $kJ$.

$A$ cylinder of gas supplied by Bharat Petroleum is assumed to contain $14 \ kg$ of butane. If a normal family requires $20,000 \ kJ$ of energy per day for cooking,how many days will the butane gas in the cylinder last? ($\Delta H_c$ of $C_4H_{10} = -2658 \ kJ/mole$)

Consider the following reaction :
$2A (g) + B (g) \rightarrow 2D(g)$
$\Delta U^{\circ} = -10 \text{ kJ mol}^{-1}$ and $\Delta S^{\circ} = -44 \text{ J K}^{-1} \text{ mol}^{-1}$ at $298 \text{ K}$.
Identify the correct option with $\Delta G^{\circ}$ for the reaction and spontaneity of the reaction at $298 \text{ K}$.
(Given : $R = 8.31 \text{ J mol}^{-1} \text{ K}^{-1}$)