Which thermochemical reaction is correct?

The enthalpy of solution of $BaCl_{2(s)}$ and $BaCl_2 \cdot 2H_2O_{(s)}$ are $-20.6 \, kJ \, mol^{-1}$ and $8.8 \, kJ \, mol^{-1}$ respectively. The enthalpy change for the reaction $BaCl_{2(s)} + 2H_2O_{(l)} \to BaCl_2 \cdot 2H_2O_{(s)}$ is $...... \, kJ \, mol^{-1}$.

What is bond enthalpy? Explain bond enthalpy in polyatomic molecules like $H_2O$.

Consider the reaction $2H_2S(g) + 3O_2(g) \rightarrow 2H_2O(l) + 2SO_2(g)$. The magnitude of enthalpy change for the reaction in $\text{kJ mol}^{-1}$ is . . . . . . . (Nearest integer). Given: $\Delta_f H^\circ(H_2S) = -20.1 \text{ kJ mol}^{-1}$, $\Delta_f H^\circ(H_2O) = -286.0 \text{ kJ mol}^{-1}$, $\Delta_f H^\circ(SO_2) = -297.0 \text{ kJ mol}^{-1}$

The combustion enthalpies of carbon,hydrogen,and methane are $-393.5 \ kJ/mole$,$-284.8 \ kJ/mole$,and $-890.4 \ kJ/mole$ respectively at $25 \ ^oC$. The value of the standard formation enthalpy of methane at that temperature is ..... $kJ/mole$.

Which of the following heat of reaction expresses the bond energy of $HCl$?