The quantum numbers $n$ and $l$ for four electrons are given as: $(1) \, n = 4, l = 1; \, (2) \, n = 4, l = 0; \, (3) \, n = 3, l = 2; \, (4) \, n = 3, l = 1$. Arrange them in increasing order of their energy.

  • A
    $(3) < (4) < (2) < (1)$
  • B
    $(4) < (2) < (3) < (1)$
  • C
    $(2) < (4) < (1) < (3)$
  • D
    $(1) < (3) < (2) < (4)$

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Explain,giving reasons,which of the following sets of quantum numbers are not possible.
$(a)$ $n=0, l=0, m_{l}=0, m_{s}=+\frac{1}{2}$
$(b)$ $n=1, l=0, m_{l}=0, m_{s}=-\frac{1}{2}$
$(c)$ $n=1, l=1, m_{l}=0, m_{s}=+\frac{1}{2}$
$(d)$ $n=2, l=1, m_{l}=0, m_{s}=-\frac{1}{2}$
$(e)$ $n=3, l=3, m_{l}=-3, m_{s}=+\frac{1}{2}$
$(f)$ $n=3, l=1, m_{l}=0, m_{s}=+\frac{1}{2}$

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