The following reactions occur for the reaction of $NO$ with $Br_2$ to form $NOBr$:
$NO_{(g)} + Br_{2_{(g)}} \rightleftharpoons NOBr_{2_{(g)}}$
$NOBr_{2_{(g)}} + NO_{(g)} \rightarrow 2 NOBr_{(g)}$
If the second reaction is the rate-determining step,the order of the reaction with respect to $NO_{(g)}$ will be:

  • A
    $1$
  • B
    $0$
  • C
    $3$
  • D
    $2$

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For the non-stoichiometric reaction $2A + B \to C + D$,the following kinetic data were obtained in three separate experiments,all at $298 \ K$.
Initial Conc. $(A)$ Initial Conc. $(B)$ Initial rate of formation of $C \ (mol \ L^{-1} \ s^{-1})$
$0.1 \ M$ $0.1 \ M$ $1.2 \times 10^{-3}$
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$0.2 \ M$ $0.1 \ M$ $2.4 \times 10^{-3}$

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$(i)$ $Cl_2 \,\underset{k_2}{\overset{k_1}{\longleftrightarrow}}\, 2Cl$
$(ii)$ $Cl + CO \,\underset{k_4}{\overset{k_3}{\longleftrightarrow}}\, COCl$
$(iii)$ $COCl + Cl_2 \xrightarrow{k_5} COCl_2 + Cl$ (slow)
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The rate constant for a second order reaction,$A \rightarrow \text{Product}$ is $1.62 \ M^{-1} \ s^{-1}$. What will be the rate of reaction when concentration of reactant is $2 \times 10^{-3} \ M$ (in $M \ s^{-1}$)?

Which of the following statements about the rate constant is $NOT$ true?

For a gaseous reaction,the rate is given by $Rate = k [A] [B]$. If the volume of the container is reduced to $1/4$ of its initial volume,the rate of the reaction will become how many times the initial rate?

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