For a weak acid $(HA)$,$pK_a = 4.5$. The $pOH$ of a buffer solution of $HA$ in which $50\%$ of the acid is ionized is:

Which of the following buffer solutions will have the highest acidic character?

$40 \ mL$ of $0.1 \ M$ ammonia solution is mixed with $20 \ mL$ of $0.1 \ M \ HCl$. What is the $pH$ of the mixture? ($pK_b$ of ammonia solution is $4.74$).

$20 \ mL$ of $0.1 \ M$ acetic acid is mixed with $50 \ mL$ of potassium acetate. $K_a$ of acetic acid $= 1.8 \times 10^{-5}$ at $27^{\circ} C$. Calculate the concentration of potassium acetate if the $pH$ of the mixture is $4.8$. (in $M$)

When $30 \ mL$ of $0.2 \ M \ NH_4OH$ is added to $30 \ mL$ of $2 \ M \ NH_4Cl$ solution. If the $pH$ of the buffer formed is $8.2$,what is the $pK_b$ of $NH_4OH$?

$A$ buffer solution is prepared by mixing equimolar acetic acid and sodium acetate. If $K_{a}$ of acetic acid is $1.78 \times 10^{-5}$,find the $pH$ of the buffer solution.