Match the items in List-$X$ with List-$Y$ and select the correct option.

List-$X$	List-$Y$
$(A)$ $A_{(g)} \rightleftharpoons B_{(g)} + \text{Heat}$	$(i)$ Equilibrium constant
$(B)$ $r_b/r_f$	$(ii)$ Favored at low temperature
$(C)$ $r_f/r_b$	$(iii)$ [Equilibrium constant]$^{-1}$
$(D)$ $2A_{(g)} + B_{(g)} \rightleftharpoons C_{(g)}$	$(iv)$ $A_{(g)} + B_{(g)} \rightleftharpoons C_{(g)} + D_{(g)}$
$(E)$ Effect of pressure	$(V)$ $\Delta n < 0$

At equilibrium for the reaction $A_{2(g)} + B_{2(g)} \rightleftharpoons 2 AB_{(g)}$,the concentrations of $A_2$,$B_2$,and $AB$ respectively are $1.5 \times 10^{-3} \ M$,$2.1 \times 10^{-3} \ M$,and $1.4 \times 10^{-3} \ M$ in a sealed vessel at $800 \ K$. What will be $K_p$ for the decomposition of $AB$ at the same temperature?

Ethyl acetate is formed by the reaction between ethanol and acetic acid and the equilibrium is represented as:
$CH_3COOH_{(l)} + C_2H_5OH_{(l)} \longleftrightarrow CH_3COOC_2H_{5(l)} + H_2O_{(l)}$
$(i)$ Write the concentration ratio (reaction quotient),$Q_c$,for this reaction (note: water is not in excess and is not a solvent in this reaction).
$(ii)$ At $293 \ K$,if one starts with $1.00 \ mol$ of acetic acid and $0.18 \ mol$ of ethanol,there is $0.171 \ mol$ of ethyl acetate in the final equilibrium mixture. Calculate the equilibrium constant.
$(iii)$ Starting with $0.5 \ mol$ of ethanol and $1.0 \ mol$ of acetic acid and maintaining it at $293 \ K$,$0.214 \ mol$ of ethyl acetate is found after sometime. Has equilibrium been reached?

For the reaction $CH_{4(g)} + 2O_{2(g)} \rightleftharpoons CO_{2(g)} + 2H_{2}O_{(g)}$ with $\Delta H = -170.8 \ kJ \ mol^{-1}$,which of the following statements is incorrect?

If the reaction is started with $NH_4COONH_{2(s)}$ and the equilibrium mixture has a total pressure of $3 \ atm$,then the $K_P$ for the reaction $NH_4COONH_{2(s)} \rightleftharpoons 2NH_{3(g)} + CO_{2(g)}$ is ..... $atm^3$.

Calculate the partial pressure of carbon monoxide from the following data:
$CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}, K_p = 8 \times 10^{-2}$
$CO_{2(g)} + C_{(s)} \rightleftharpoons 2CO_{(g)}, K_p = 2$