The equilibrium of the reaction $2A_{(s)} + 3B_{(g)} \rightleftharpoons 3C_{(g)} + D_{(g)} + Q$ is represented as shown. If the pressure on the system is reduced to half of its original value,then:

  • A
    The concentrations of $C$ and $D$ decrease.
  • B
    The concentrations of $C$ and $D$ increase.
  • C
    The concentration of $D$ decreases.
  • D
    The concentrations of all remain constant.

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In which of the following reactions at equilibrium,the position of the equilibrium shifts towards the products,if the total pressure is increased?
$(I)$ $X_{2(g)} + 3Y_{2(g)} \rightleftharpoons 2XY_{3(g)}$
$(II)$ $X_{2(g)} + Y_{2(g)} \rightleftharpoons 2XY_{(g)}$
$(III)$ $X_{2(g)} + Z_{2(g)} \rightleftharpoons 2XZ_{(g)}$
$(IV)$ $X_{2(g)} + Y_{4(g)} \rightleftharpoons 2XY_{2(g)}$

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