Which of the following mixtures is called an acidic buffer?

Which of the following mixtures gives a buffer solution with $pH = 9.25$?
Given: $pK_{b} (NH_{4}OH) = 4.75$

The $pK_b$ of $CN^{\Theta}$ is $4.7$. The $pH$ of a solution prepared by mixing $2.5 \ mol$ of $KCN$ and $2.5 \ mol$ of $HCN$ in water and making the total volume up to $500 \ mL$ is:

The dissociation constant of a weak acid is $1 \times 10^{-4}.$ In order to prepare a buffer solution with a $pH = 5,$ the $[Salt]/[Acid]$ ratio should be

$A$ buffer solution has equal volumes of $0.2 \ M \ NH_4OH$ and $0.02 \ M \ NH_4Cl$. The $pK_b$ of the base is $5$. The $pH$ is

$0.1 \ mol$ of $CH_3NH_2$ $(K_b = 5 \times 10^{-4})$ is mixed with $0.08 \ mol$ of $HCl$ and diluted to $1 \ L$. What will be the $[H^{+}]$ concentration in the solution?