Which of the following substances does not dissolve in a sodium carbonate solution?

The number of isomeric ethers with molecular formula $C_4H_{10}O$ is:

Match the reactions given in Column-$I$ with the names of the products and reactions given in Column-$II$.

Column-$I$ (Reaction)	Column-$II$ (Product and Reaction Name)
$A$. Phenol $+$ dilute $HNO_3$	$i$. Mononitrophenol,Nitration
$B$. Phenol $+$ Bromine water	$ii$. $2,4,6$-Tribromophenol,Bromination
$C$. Phenol $+$ $Na_2Cr_2O_7/H_2SO_4$	$iii$. Benzoquinone,Oxidation
$D$. Sodium phenoxide $+$ $CO_2$ followed by $H^+$	$iv$. Salicylic acid,Kolbe reaction

Number of isomeric compounds with molecular formula $C_9H_{10}O$ which $(i)$ do not dissolve in $NaOH$ $(ii)$ do not dissolve in $HCl$ $(iii)$ do not give orange precipitate with $2,4-DNP$ $(iv)$ on hydrogenation give identical compound with molecular formula $C_9H_{12}O$ is $...........$

What is the product of the reaction shown below?

What will be the composition of the resulting solution when ethyl acetate is mixed with aqueous sodium chloride?