$KMnO_4$ (acidified) $+ HCl \rightarrow H_2O + X_{(g)},$ $X$ is a

In which of the following reactions, chlorine acts as an oxidising agent?
$(i)$ $CH_3CH_2OH + Cl_2 \longrightarrow CH_3CHO + HCl$
(ii) $CH_3CHO + Cl_2 \longrightarrow CCl_3CHO + HCl$
(iii) $CH_4 + Cl_2 \stackrel{hv}{\longrightarrow} CH_3Cl + HCl$
The correct answer is

Consider the reactions:
$2S_2O_3^{2-}{(aq)} + I_{2(s)} \to S_4O_6^{2-}{(aq)} + 2I^{-}{(aq)}$
$S_2O_3^{2-}{(aq)} + 2Br_{2(l)} + 5H_2O_{(l)} \to 2SO_4^{2-}{(aq)} + 4Br^{-}{(aq)} + 10H^{+}{(aq)}$
Why does the same reductant,thiosulphate,react differently with iodine and bromine?

Iron is dropped in dilute $HNO_3$,it gives:

Which of the following act as an oxidising as well as a reducing agent?

For the following redox reaction, find the correct statement: $Sn^{2+} + 2Fe^{3+} \rightarrow Sn^{4+} + 2Fe^{2+}$