$A$ $2.0 \, g$ sample containing $MnO_2$ is treated with $HCl$ liberating $Cl_2$. The $Cl_2$ gas is passed into a solution of $KI$ and $60.0 \, mL$ of $0.1 \, M \, Na_2S_2O_3$ is required to titrate the liberated iodine. The percentage of $MnO_2$ in the sample is $.....$ (Nearest integer).
[Atomic masses (in $u$): $Mn = 55, Cl = 35.5, O = 16, I = 127, Na = 23, K = 39, S = 32$]

Which of the following cannot give iodometric titrations?

Identify the correct statements:
$A$. Hydrated salts can be used as primary standard.
$B$. Primary standard should not undergo any reaction with air.
$C$. Reactions of primary standard with another substance should be instantaneous and stoichiometric.
$D$. Primary standard should not be soluble in water.
$E$. Primary standard should have low relative molar mass.
Choose the correct answer from the options given below :

What weight of ferrous ammonium sulphate is needed to prepare $100 \, mL$ of $0.1 \, N$ solution? (mol. wt. $392$)

$10 \ cm^{3}$ of $0.1 \ N$ monobasic acid requires $15 \ cm^{3}$ of sodium hydroxide solution whose normality is: (in $N$)

Why is it necessary to wash the precipitate before measuring it quantitatively?