$A$ buffer solution is a mixture of

$A$ solution is prepared by mixing $0.01 \ mol$ each of $H_2CO_3$,$NaHCO_3$,$Na_2CO_3$,and $NaOH$ in $100 \ mL$ of water. The $pH$ of the resulting solution is. . . . . . .
[Given : $pK_{a1}$ and $pK_{a2}$ of $H_2CO_3$ are $6.37$ and $10.32$,respectively; $\log 2=0.30$ ]

At $25 \, ^\circ C$,the $K_a$ for $HCN$ is $5 \times 10^{-10}$. What volume (in $mL$) of $5 \, M \, KCN$ solution must be added to $10 \, mL$ of $2 \, M \, HCN$ solution to maintain a constant $pH$ of $9$?

If $12.5 \ mL$ of $0.1 \ M$ $KOH$ is added into $50 \ mL$ of $0.1 \ M$ $CH_3COOH$ solution,then what would be the final $pH$? $(K_a(CH_3COOH) = 2 \times 10^{-5})$

Given below are two statements:
Statement $I$: $A$ buffer solution is the mixture of a salt and an acid or a base mixed in any particular quantities.
Statement $II$: Blood is a naturally occurring buffer solution whose $pH$ is maintained by $H_2CO_3 / HCO_3^{-}$ concentrations.
In the light of the above statements,choose the correct answer from the options given below.

Calculate $pH$ of the solution obtained by mixing $50 \ mL$ of $0.2 \ M$ $NH_4Cl$ solution and $75 \ mL$ of $0.1 \ M$ $NaOH$ solution. Given $pK_b$ for aqueous $NH_3$ is $4.74$.