$A$ new carbon-carbon bond formation is possible in

  • A
    Cannizzaro reaction
  • B
    Friedel-Crafts alkylation
  • C
    Reimer-Tiemann reaction
  • D
    Both $(b)$ and $(c)$

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The number of isomeric ethers with molecular formula $C_4H_{10}O$ is:

Which of the following compounds will give a tribromo derivative upon reaction with bromine water?

Match the structures in Column-$I$ with their common names in Column-$II$ and $\text{IUPAC}$ names in Column-$III$.
Column-$I$ Column-$II$ Column-$III$
$(A) \ HO-CH_2-CH_2OH$ $(1) \ \text{sec-Butyl alcohol}$ $(i) \ \text{Ethane-1,2-diol}$
$(B) \ CH_3-CH(OH)-CH_2CH_3$ $(2) \ \text{Isopropyl alcohol}$ $(ii) \ \text{2,2-Dimethylpropan-1-ol}$
$(C) \ CH_3-CH(OH)-CH_3$ $(3) \ \text{Ethylene glycol}$ $(iii) \ \text{Butan-2-ol}$
$(D) \ (CH_3)_3C-CH_2OH$ $(4) \ \text{Neopentyl alcohol}$ $(iv) \ \text{Propan-2-ol}$

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An organic compound $A$ $(C_{6}H_{6}O)$ gives a dark green coloration with ferric chloride. On treatment with $CHCl_{3}$ and $KOH$,followed by acidification,it gives compound $B$. Compound $B$ can also be obtained from compound $C$ on reaction with pyridinium chlorochromate $(PCC)$. Identify $A, B$ and $C$.

$HOOC-COOH + HO^{18}CH_2-CH_2^{18}OH \xrightarrow[H^+]{\Delta} (A)$; Product $(A)$ is:

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