$A$ process is taking place at constant temperature and pressure. Then

  • A
    $\Delta H = \Delta E$
  • B
    $\Delta H = T\Delta S$
  • C
    $\Delta H = 0$
  • D
    $\Delta S = 0$

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For a reaction at $25 \, ^oC$,the enthalpy change and entropy change are $-11.7 \times 10^3 \, J \, mol^{-1}$ and $-105 \, J \, mol^{-1} \, K^{-1}$ respectively. What is the Gibbs free energy in $kJ$?

Calculate the maximum work done in expanding $16 \ g$ of oxygen $(O_2)$ at $300 \ K$ and occupying a volume of $5 \ dm^3$ isothermally until the volume becomes $25 \ dm^3$. (in $J$)

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Describe Gibbs energy and spontaneity.

At $273 \ K$ the maximum work done when pressure on $10 \ g$ of hydrogen is reduced from $10 \ atm$ to $1 \ atm$ under isothermal,reversible conditions is (Assume the gas behaves ideally) $(R=8.3 \ J \ K^{-1} \ mol^{-1})$

Compare the following criteria for spontaneity of a reaction based on the values of $\Delta_{\text{r}}H^0$,$\Delta_{\text{r}}S^0$,and $\Delta_{\text{r}}G^0$:
$\Delta_{\text{r}}H^0$$\Delta_{\text{r}}S^0$$\Delta_{\text{r}}G^0$Description
$(a) (+)$$(-)$$(+)$$(i) \text{ Non-spontaneous at all temperatures}$
$(b) (-)$$(-)$$(-)$$(ii) \text{ Spontaneous at low temperatures}$
$(c) (-)$$(+)$$(-)$$(iii) \text{ Spontaneous at all temperatures}$

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