$A$ pure substance (solid,liquid,or gas) of constant composition is taken in a closed container. Select the correct plot if pressure is applied at constant temperature in the absence of non-expansion work.

State $1 \longleftarrow$ State $2 \longleftarrow$ State $3$
$\left(\begin{array}{c} T=300 \ K \\ P=15 \ bar \\ 1 \ mole \end{array}\right) \left(\begin{array}{c} T=300 \ K \\ P=10 \ bar \\ 1 \ mole \end{array}\right) \left(\begin{array}{c} T=300 \ K \\ P=5 \ bar \\ 1 \ mole \end{array}\right)$
The above shows a cyclic process. Calculate the total work done during one complete cycle. (Assume a single step to reach the next state).

The enthalpy of sublimation of $I_{2(s)}$ is $57.3 \, kJ \, mol^{-1}$ and the enthalpy of fusion is $15.5 \, kJ \, mol^{-1}$. The enthalpy of vaporization of $I_2$ is ..................... $kJ \, mol^{-1}$. (in $.8$)

Enthalpy of hydrogenation of one mole of benzene to cyclohexane is
$[$Resonance energy of benzene $= -150.4 \ kJ / mol$.
Enthalpy of hydrogenation of cyclohexene $= -119.5 \ kJ / mol$ $]$

The molar heat capacity for an ideal gas at constant pressure is $20.785 \ J \ K^{-1} \ mol^{-1}$. The change in internal energy is $5000 \ J$ upon heating it from $300 \ K$ to $500 \ K$. The number of moles of the gas is [Nearest integer] (Given: $R = 8.314 \ J \ K^{-1} \ mol^{-1}$)

The standard enthalpies of formation of $1,3-butadiene(g)$,$CO_{2(g)}$,and $H_2O_{(l)}$ at $298 \ K$ are $-30$,$-94$,and $-68 \ kcal/mol$ respectively. If the magnitude of resonance enthalpies of $1,3-butadiene$ and $CO_2$ are $10$ and $20 \ kcal/mol$ respectively,the enthalpy of combustion of $1,3-butadiene(g)$ at $298 \ K$ is $........ \ kcal/mol$. (Enthalpy of vaporization of $H_2O_{(l)}$ at $298 \ K = 10 \ kcal/mol$)