Amides may be converted into amines by a reac | vedclass

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(C) The conversion of amides into amines is known as the $Hofmann$ bromamide degradation reaction.In this reaction,an amide is treated with bromine in

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Hofmann

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(C) The conversion of amides into amines is known as the $Hofmann$ bromamide degradation reaction.In this reaction,an amide is treated with bromine in an aqueous or ethanolic solution of sodium hydroxide $(NaOH)$ or potassium hydroxide $(KOH)$.The general reaction is: $R-CONH_2 + Br_2 + 4KOH \longrightarrow R-NH_2 + K_2CO_3 + 2KBr + 2H_2O$.For example,the conversion of acetamide $(CH_3CONH_2)$ into methylamine $(CH_3NH_2)$ is represented as: $CH_3CONH_2 + Br_2 + 4KOH \longrightarrow CH_3NH_2 + K_2CO_3 + 2KBr + 2H_2O$.

Amides may be converted into amines by a reaction named after :

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