Ammonia under a pressure of $15 \ atm$ at $27 \ ^{\circ}C$ is heated to $347 \ ^{\circ}C$ in a closed vessel in the presence of a catalyst. Under these conditions,$NH_3$ is partially decomposed according to the equation,$2NH_3 \rightleftharpoons N_2 + 3H_2$. The vessel is such that the volume remains constant,and the pressure increases to $50 \ atm$. Calculate the percentage of $NH_3$ actually decomposed.

The reaction,$2SO_{2(g)} + O_{2(g)} \rightleftharpoons 2SO_{3(g)}$ is carried out in a $1 \ dm^3$ vessel and $2 \ dm^3$ vessel separately. The ratio of the reaction velocities will be

$X_{2(g)} + Y_{2(g)} \rightleftharpoons 2Z_{(g)}$
$X_{2(g)}$ and $Y_{2(g)}$ are added to a $1 \ L$ flask and it is found that the system attains the above equilibrium at $T \ K$ with the number of moles of $X_{2(g)}$, $Y_{2(g)}$ and $Z_{(g)}$ being $3$, $3$ and $9 \ mol$ respectively (equilibrium moles). Under these conditions of equilibrium, $10 \ mol$ of $Z_{(g)}$ is added to the flask and the temperature is maintained at $T \ K$. Then the number of moles of $Z_{(g)}$ in the flask when the new equilibrium is established is . . . . . . . (Nearest integer).

The following reaction is performed at $298 \, K$.
$2 NO_{(g)} + O_{2(g)} \rightleftharpoons 2 NO_{2(g)}$
The standard free energy of formation of $NO_{(g)}$ is $86.6 \, kJ/mol$ at $298 \, K$. What is the standard free energy of formation of $NO_{2(g)}$ at $298 \, K$? $(K_p = 1.6 \times 10^{12})$

Which one of the following statements is correct for a reversible reaction? $A$ catalyst

The two substances $A$ and $B$ are in equilibrium with $C$ and $D$ as $2A + B \rightleftharpoons 3C + 2D$. If the initial pressure of $A$ and $B$ are in the ratio of $4:1$ and at equilibrium,the partial pressures of $A$ and $D$ are equal,find the correct relation.