Among the second period elements,the actual ionization enthalpies are in the order $Li < B < Be < C < O < N < F < Ne$. Explain why:
$(i)$ $Be$ has higher $\Delta_{i}H$ than $B$.
$(ii)$ $O$ has lower $\Delta_{i}H$ than $N$ and $F$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) $(i)$ During the process of ionization,the electron to be removed from a beryllium atom is a $2s$-electron,whereas the electron to be removed from a boron atom is a $2p$-electron.
$2s$-electrons are more strongly attracted to the nucleus than $2p$-electrons. Therefore,more energy is required to remove a $2s$-electron of beryllium than that required to remove a $2p$-electron of boron. Hence,beryllium has a higher $\Delta_{i}H$ than boron.
$(ii)$ In nitrogen $(1s^2 2s^2 2p^3)$,the three $2p$-electrons occupy three different atomic orbitals,representing a stable half-filled configuration. In oxygen $(1s^2 2s^2 2p^4)$,two of the four $2p$-electrons occupy the same $2p$-orbital,resulting in increased electron-electron repulsion. Consequently,the energy required to remove an electron from oxygen is less than that required for nitrogen.
Fluorine has a higher effective nuclear charge than oxygen due to an additional proton in the same shell. This results in a stronger attraction for valence electrons,making it harder to remove an electron from fluorine compared to oxygen. Thus,oxygen has a lower $\Delta_{i}H$ than both nitrogen and fluorine.

Explore More

Similar Questions

(in $\%$)

If $\sin ^{-1} x - \cos ^{-1} x = \frac{\pi}{6}$,then $x$ is equal to

If the number of diagonals of a regular polygon is $35$,then the number of sides of the polygon is

How many geometrical isomers are possible for the complex $[Mab(AB)_2]^{\pm n}$?

The foci of the ellipse $\frac{x^2}{16} + \frac{y^2}{b^2} = 1$ and the hyperbola $\frac{x^2}{144} - \frac{y^2}{81} = \frac{1}{25}$ coincide. Then the value of $b^2$ is

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo