Amongst the following statements regarding adsorption,those that are valid are :
$(a)$ $\Delta H$ becomes less negative as adsorption proceeds.
$(b)$ On a given adsorbent,ammonia is adsorbed more than nitrogen gas.
$(c)$ On adsorption,the residual force acting along the surface of the adsorbent increases.
$(d)$ With increase in temperature,the equilibrium concentration of adsorbate increases.

  • A
    $(b)$ and $(c)$
  • B
    $(a)$ and $(b)$
  • C
    $(d)$ and $(a)$
  • D
    $(c)$ and $(d)$

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Which plot is the adsorption isobar for chemisorption where $x$ is the amount of gas adsorbed on mass $m$ at temperature $T$?

Plot of $\log \left( \frac{x}{m} \right)$ against $\log P$ is a straight line inclined at an angle of $45^{\circ}$. When the pressure is $0.5 \ atm$ and Freundlich parameter $(K)$ is $10$,then the amount of solute adsorbed per gram of adsorbent is .......... $g$ $(\log 5 = 0.699)$.

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Assertion : The relation $\frac{x}{m} = k \cdot p^{1/n}$ is known as Freundlich adsorption isotherm,where $x$ is the mass of gas adsorbed by $m$ grams of adsorbent,$p$ is the equilibrium pressure,$k$ and $n$ are constants for a given system and temperature.
Reason : When several substances have the same value of $\frac{1}{n}$,the lines by which their adsorption isotherms can be represented will meet at a point.

$CH_4$ is adsorbed on $1 \ g$ charcoal at $0^{\circ} C$ following the Freundlich adsorption isotherm. $10.0 \ mL$ of $CH_4$ is adsorbed at $100 \ mm$ of $Hg$,whereas $15.0 \ mL$ is adsorbed at $200 \ mm$ of $Hg$. The volume of $CH_4$ adsorbed at $300 \ mm$ of $Hg$ is $10^x \ mL$. The value of $x$ is $....\times 10^{-2}$ (Nearest integer). [Use $\log_{10} 2=0.3010, \log_{10} 3=0.4771$]

The extent of adsorption of a gas on a solid depends on:

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