An amine $(X)$ is prepared by ammonolysis of benzyl chloride. On adding $p-$toluenesulphonyl chloride to it,the solution remains clear. The molar mass of the amine $(X)$ formed is $g \ mol^{-1}$. (Given molar mass in $g \ mol^{-1}$: $C=12, H=1, O=16, N=14, S=32, Cl=35.5$)

$X \ g$ of ethanamine was subjected to reaction with $NaNO_2 / HCl$ followed by hydrolysis to liberate $N_2$ and $HCl$. The $HCl$ generated was completely neutralized by $0.2 \ mol$ of $NaOH$. $X$ is . . . .

Primary and secondary amines can be distinguished by $:-$

$A$ colourless substance $'A'$ $(C_6H_7N)$ is sparingly soluble in water and gives a water-soluble compound $'B'$ on treating with mineral acid. On reacting with $CHCl_3$ and alcoholic potash,$'A'$ produces an obnoxious smell due to the formation of compound $'C'$. Reaction of $'A'$ with benzenesulphonyl chloride gives compound $'D'$ which is soluble in alkali. With $NaNO_2$ and $HCl$,$'A'$ forms compound $'E'$ which reacts with phenol in an alkaline medium to give an orange dye $'F'$. Identify compounds $'A'$ to $'F'$.

Among the compounds given below,the order of basicity is:
$(I)$ Piperidine
$(II)$ Pyridine
$(III)$ Morpholine
$(IV)$ Pyrrole

Which of the following reactions will not give a primary amine?