An ideal gas expands adiabatically against vacuum. Which of the following is correct for the given process?

Two moles of an ideal gas are allowed to expand from a volume of $10 \ dm^3$ to $2 \ m^3$ at $300 \ K$ against a pressure of $101.325 \ kPa$. Calculate the work done. (in $kJ$)

Consider the reaction at $298 \ K$:
$H_{2(g)} + Cl_{2(g)} \to 2HCl_{(g)}, \Delta H^o = -185 \ kJ$
What is $\Delta U^o$ for this reaction? .....$kJ$

Standard enthalpy of vaporisation $\Delta_{vap}H^o$ for water at $100\ ^oC$ is $40.66\ kJ\ mol^{-1}.$ The internal energy of vaporisation of water at $100\ ^oC$ (in $kJ\ mol^{-1}$) is ............... $kJ\ mol^{-1}$ (Assume water vapour to behave like an ideal gas)

The enthalpy of vapour is $10 \ kcal/mole$ higher than liquid at $350 \ K$ and $2 \ atm$. Under given conditions,the difference in internal energy of vapour and liquid will be $...... \ cal$.

When $1 \, \text{mol}$ of a gas is heated at constant volume,the temperature increases from $298 \, K$ to $308 \, K$. If the heat supplied to the gas is $500 \, J$,which of the following statements is correct?