Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$Na_2S_2O_3 + BaCl_2 \longrightarrow BaS_2O_3 \downarrow + 2NaCl$

In the reaction between moist $SO_2$ and acidified permanganate solution:

Identify the substance oxidised,reduced,oxidising agent,and reducing agent for each of the following reactions:
$(a)$ $2 AgBr_{(s)} + C_6 H_6 O_{2(aq)} \rightarrow 2 Ag_{(s)} + 2 HBr_{(aq)} + C_6 H_4 O_{2(aq)}$
$(b)$ $HCHO_{(l)} + 2 [Ag(NH_3)_2]^+_{(aq)} + 3 OH^-_{(aq)}$ $\rightarrow 2 Ag_{(s)} + HCOO^-_{(aq)} + 4 NH_{3(aq)} + 2 H_2 O_{(l)}$
$(c)$ $HCHO_{(l)} + 2 Cu^{2+}_{(aq)} + 5 OH^-_{(aq)} \rightarrow Cu_2 O_{(s)} + HCOO^-_{(aq)} + 3 H_2 O_{(l)}$
$(d)$ $N_2 H_{4(l)} + 2 H_2 O_{2(l)} \rightarrow N_{2(g)} + 4 H_2 O_{(l)}$
$(e)$ $Pb_{(s)} + PbO_{2(s)} + 2 H_2 SO_{4(aq)} \rightarrow 2 PbSO_{4(s)} + 2 H_2 O_{(l)}$

$50 \ cm^{3}$ of $0.04 \ M \ K_{2}Cr_{2}O_{7}$ in acidic medium oxidizes a sample of $H_{2}S$ gas to sulphur. The volume of $0.03 \ M \ KMnO_{4}$ required to oxidize the same amount of $H_{2}S$ gas to sulphur in acidic medium is: (in $cm^{3}$)

To measure the quantity of $MnCl_2$ dissolved in an aqueous solution,it was completely converted to $KMnO_4$ using the reaction,
$MnCl_2 + K_2S_2O_8 + H_2O \longrightarrow KMnO_4 + H_2SO_4 + HCl$ (equation not balanced).
Few drops of concentrated $HCl$ were added to this solution and gently warmed. Further,oxalic acid $(225 \ mg)$ was added in portions till the colour of the permanganate ion disappeared. The quantity of $MnCl_2$ (in $mg$) present in the initial solution is . . . . . . . . . (Atomic weights in $g \ mol^{-1}: Mn = 55, Cl = 35.5$ )

To an acidified dichromate solution,a pinch of $Na_2O_2$ is added and shaken. What is observed?