At $T$ $(K)$,the equilibrium constant for the reaction $H_{2(g)} + Br_{2(g)} \rightleftharpoons 2 HBr_{(g)}$ is $1.6 \times 10^5$. If $10 \ bar$ of $HBr$ is introduced into a sealed vessel at $T$ $(K)$,the equilibrium pressure of $HBr$ (in $bar$) is approximately

  • A
    $10.20$
  • B
    $10.95$
  • C
    $9.95$
  • D
    $11.95$

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Write a relation between $\Delta G$ and $Q$ and define the meaning of each term and answer the following:
$(a)$ Why a reaction proceeds forward when $Q < K$ and no net reaction occurs when $Q = K$.
$(b)$ Explain the effect of increase in pressure in terms of reaction quotient $Q$.
For the reaction: $CO_{(g)} + 3H_{2(g)} \rightleftharpoons CH_{4(g)} + H_{2}O_{(g)}$

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At $1000 \ K$ in a $0.654 \ L$ vessel,$CaCO_{3(s)}$ is taken. For the reaction $CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}$,the equilibrium constant $K_p$ is $3.9 \times 10^{-2} \ bar$. Find the weight of $CaO$ produced at equilibrium. $(Ca=40, C=12, O=16)$

For the reversible reaction $2NO_2 \leftrightarrow[K_2]{K_1} N_2O_4$,the rate of disappearance of $NO_2$ is given by:

Thermal decomposition of gaseous $X_2$ to gaseous $X$ at $298 \ K$ takes place according to the following equation :
$X_{2(g)} \rightleftharpoons 2 X_{(g)}$
The standard reaction Gibbs energy,$\Delta_r G^{\circ}$,of this reaction is positive. At the start of the reaction,there is one mole of $X_2$ and no $X$. As the reaction proceeds,the number of moles of $X$ formed is given by $\beta$. Thus,$\beta_{\text{equilibrium}}$ is the number of moles of $X$ formed at equilibrium. The reaction is carried out at a constant total pressure of $2 \ bar$. Consider the gases to behave ideally. (Given : $R=0.083 \ L \ bar \ K^{-1} \ mol^{-1}$)
$(1)$ The equilibrium constant $K_P$ for this reaction at $298 \ K$,in terms of $\beta_{\text{equilibrium}}$,is
$(A)$ $\frac{8 \beta_{\text{equilibrium}}^2}{2-\beta_{\text{equilibrium}}}$ $(B)$ $\frac{8 \beta_{\text{equilibrium}}^2}{4-\beta_{\text{equilibrium}}^2}$ $(C)$ $\frac{4 \beta_{\text{equilibrium}}^2}{2-\beta_{\text{equilibrium}}}$ $(D)$ $\frac{4 \beta_{\text{equilibrium}}^2}{4-\beta_{\text{equilibrium}}^2}$
$(2)$ The $INCORRECT$ statement among the following,for this reaction,is
$(A)$ Decrease in the total pressure will result in formation of more moles of gaseous $X$
$(B)$ At the start of the reaction,dissociation of gaseous $X_2$ takes place spontaneously
$(C)$ $\beta_{\text{equilibrium}}=0.7$
$(D)$ $K_c < 1$

One mole of $O_{2(g)}$ and two moles of $SO_{2(g)}$ were heated in a closed vessel of $1 \, L$ capacity at $1098 \, K$. At equilibrium,$1.6 \, moles$ of $SO_{3(g)}$ were found. The equilibrium constant $K_c$ of the reaction would be

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