At $1000 \ K$,the equilibrium constant for the reaction $CO_{2(g)} + H_{2(g)} \rightleftharpoons CO_{(g)} + H_2O_{(g)}$ is $0.53$. In a one litre vessel,at equilibrium the mixture contains $0.25 \ mole$ of $CO$,$0.5 \ mole$ of $CO_2$,$0.6 \ mole$ of $H_2$ and $x \ moles$ of $H_2O$. The value of $x$ is

Solid $KClO_3$ is taken in a container maintained at a constant pressure of $1 \ atm$. Upon heating,the following equilibrium is obtained:
$2KClO_{3(s)} \rightleftharpoons 2KCl_{(s)} + 3O_{2(g)}$
If $\Delta H^o = 25 \ kcal/mol$ and $\Delta S^o = 50 \ cal/K$,at what temperature will equilibrium be established in the container? (Ignore variation of $\Delta H^o$ and $\Delta S^o$ with temperature.) $......K$

At $500 \ K$,for a reversible reaction $A_{2(g)} + B_{2(g)} \rightleftharpoons 2 AB_{(g)}$ in a closed container,$K_C = 2 \times 10^{-5}$. In the presence of a catalyst,the equilibrium is attained $10$ times faster. The equilibrium constant $K_C$ in the presence of a catalyst at the same temperature is:

$A$ gaseous reaction $A_{2(g)} \to B_{(g)} + \frac{1}{2} C_{(g)}$ shows an increase in pressure from $100 \ mm$ of $Hg$ to $120 \ mm$ of $Hg$ in $5 \ min$. What will be the rate of disappearance of $A_2$ in $mm$ of $Hg/min$?

State the important biological and environmental chemical equilibrium with examples.

At $227 \, ^\circ C$,$60 \%$ of $PCl_5$ dissociates in a $2 \, L$ container. The value of $K_p$ is equal to $...... R$.