Attainment of the equilibrium $A_{(g)} \rightleftharpoons 3C_{(g)} + 2B_{(g)}$ gave the following graph. Find the correct option. $(\text{Percentage dissociation} = \text{fraction dissociated} \times 100)$

  • A
    At $t = 5 \ s$ equilibrium has been reached and $K_c = 128 \ (mol/litre)^2$
  • B
    At $t = 5 \ s$ equilibrium has been reached and $\text{percentage dissociation}$ of $A$ is $70\%$
  • C
    At $t = 5 \ s$ equilibrium has been reached and $\text{percentage dissociation}$ of $A$ is $30\%$
  • D
    None of these

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At $473 \ K$, equilibrium constant $K_{c}$ for decomposition of phosphorus pentachloride, $PCl_{5}$, is $8.3 \times 10^{-3}$. If decomposition is depicted as,
$PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}, \Delta_{r}H^{\Theta} = 124.0 \ kJ \ mol^{-1}$
$(a)$ Write an expression for $K_{c}$ for the reaction.
$(b)$ What is the value of $K_{c}$ for the reverse reaction at the same temperature?
$(c)$ What would be the effect on $K_{c}$ if $(i)$ more $PCl_{5}$ is added $(ii)$ pressure is increased $(iii)$ the temperature is increased?

$10 \%$ of $PCl_5$ decomposes at a definite temperature and $4 \ atm$ pressure. At the same temperature,if $20 \%$ of $PCl_5$ decomposes,find the pressure. (Temperature remains constant.) (in $atm$)

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One mole of $H_2O$ and one mole of $CO$ are taken in a $10 \ L$ vessel and heated to $725 \ K$. At equilibrium,$40 \%$ of water (by mass) reacts with $CO$ according to the equation:
$H_2O_{(g)} + CO_{(g)} \longleftrightarrow H_{2(g)} + CO_{2(g)}$
Calculate the equilibrium constant $(K_c)$ for the reaction.

For a reaction,$A \rightleftharpoons P$,the plots of $[A]$ and $[P]$ with time at temperatures $T_1$ and $T_2$ are given below. If $T_2 > T_1$,the correct statement$(s)$ is (are) (Assume $\Delta H^{\ominus}$ and $\Delta S^{\ominus}$ are independent of temperature and ratio of $\ln K$ at $T_1$ to $\ln K$ at $T_2$ is greater than $T_2 / T_1$. Here $H, S, G$ and $K$ are enthalpy,entropy,Gibbs energy and equilibrium constant,respectively.)
$(A)$ $\Delta H^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(B)$ $\Delta G^{\ominus} < 0, \Delta H^{\ominus} > 0$
$(C)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(D)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} > 0$

From the given data of equilibrium constants for the following reactions:
$(1) \ CO_{2(g)} + H_{2(g)} \rightleftharpoons CO_{(g)} + H_2O_{(g)} \ ; \ K_1$
$(2) \ CO_{(g)} + H_2O_{(g)} \rightleftharpoons CO_{2(g)} + H_{2(g)} \ ; \ K_2$
Wait,the provided question text has a typo in the reaction equations. Assuming the standard problem format where we relate equilibrium constants for reverse or combined reactions,if the target reaction is the same as reaction $(1)$,the answer is $K_1$. However,based on the options provided,this is likely a question asking for the relationship between $K_1$ and $K_2$ where reaction $(2)$ is the reverse of reaction $(1)$. If reaction $(2)$ is the reverse of reaction $(1)$,then $K_2 = \frac{1}{K_1}$. Given the options,please re-verify the input. Assuming the question asks for the equilibrium constant of a reaction derived from these,if the target reaction is $CO_{(g)} + H_2O_{(g)} \rightleftharpoons CO_{2(g)} + H_{2(g)}$,the answer is $K_1^{-1}$. Given the options,if we assume the target reaction is the reverse of reaction $(1)$,then $K = \frac{1}{K_1}$.

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