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Cinnabar is an ore of which of the following?

The one that is not a carbonate is

Which of the following are carbonate ores?
$I$. Magnetite
$II$. Kaolinite
$III$. Siderite
$IV$. Calamine

The ore in which sulphide is absent :
$(I)$ Cuprite
$(II)$ Argentite
$(III)$ Pyrites
$(IV)$ Siderite

What is the formula of pyrolusite ore?

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